6.1 Newtonian viscosity and momentum transport

Viscosity is the resistance a fluid offers to being sheared. It is the first of three classical transport processes — of momentum, heat, and matter — that this chapter shows to share a single mathematical form. This lesson defines viscosity operationally, then explains it microscopically as the diffusion of momentum.

The shear experiment

Confine a fluid between two parallel plates separated by a gap hh. Hold the lower plate fixed and drag the upper one sideways at velocity UU. The fluid in contact with each plate moves with it (the no-slip condition), and in steady state the velocity varies linearly across the gap,

u(y)  =  Uyh.u(y) \;=\; U\,\frac{y}{h}.

To keep the top plate moving, a tangential force per unit area — the shear stress τ\tau — must be applied. A fluid is Newtonian when that stress is proportional to the velocity gradient it sustains:

τ  =  μdudy.\tau \;=\; \mu\,\frac{du}{dy}.
U → →fixedτ = μU/hu(y) = U y/h, τ = μU/h = 1.000
U1.00
μ1.00
h1.00
τ = μU/h1.000

The top plate drags the fluid; the bottom plate holds it still. In steady state the velocity is *linear* in y — Couette flow — and the shear stress on either plate is τ = μ ∂u/∂y = μU/h. This is the operational definition of viscosity: the force per unit area required to slide one plate over the other at unit velocity, divided by μ.

The constant of proportionality is the dynamic viscosity μ\mu, with units of Pas\text{Pa}\cdot\text{s}. Water at 2020^\circC has μ103Pas\mu \approx 10^{-3}\,\text{Pa}\cdot\text{s}; air has μ1.8×105Pas\mu \approx 1.8\times 10^{-5}\,\text{Pa}\cdot\text{s}, some fifty times less. Many common fluids are Newtonian to excellent approximation; polymers, suspensions, and pastes are not, and their nonlinear τ(du/dy)\tau(du/dy) is the subject of rheology.

Viscosity as a diffusivity of momentum

The shear stress is more than a definition — it is a momentum flux. Each layer of fluid carries xx-momentum, and the faster layers hand momentum to the slower ones across the planes between them. The stress τ\tau is exactly the rate at which xx-momentum is transported per unit area in the yy-direction. Read this way, τ=μdu/dy\tau = \mu\,du/dy says momentum flux is proportional to the gradient of momentum density — the same form a diffusion law takes.

The point is made dimensionally by the kinematic viscosity

ν  =  μρ,\nu \;=\; \frac{\mu}{\rho},

which has units of m2/s\text{m}^2/\text{s} — the units of a diffusion coefficient. Viscosity is the diffusivity of momentum: a velocity disturbance spreads sideways through a fluid exactly as a drop of dye spreads through still water, governed by ν\nu.

The microscopic origin

For a gas the mechanism is explicit, and follows from the kinetic theory chapter. Molecules in the faster-moving layer thermally wander into the slower layer carrying their surplus momentum, while slower molecules wander the other way; the net momentum exchanged per unit area per unit time is the viscous stress. Estimating the momentum carried across a mean free path \ell by molecules of mean speed v\langle v\rangle gives

μ    13ρv.\mu \;\sim\; \tfrac13\,\rho\,\langle v\rangle\,\ell.

This estimate has a striking consequence. The mean speed rises with temperature, vT\langle v\rangle \propto \sqrt{T}, while the product ρ\rho\,\ell is independent of density (a denser gas has more carriers but a shorter free path, and the two cancel). So gas viscosity rises with temperature and is independent of pressure — both counterintuitive if one pictures viscosity as molecular stickiness, both confirmed by experiment, and both correctly predicted by the momentum-transport picture. Liquids, where molecules are caged by their neighbours rather than flying freely, behave oppositely: their viscosity falls steeply as temperature rises.